Methods of improving hydraulic fracture network

ABSTRACT

The complexity of a fracture network may be enhanced during a hydraulic fracturing operation by monitoring operational parameters of the fracturing job and altering stress conditions in the well in response to the monitoring of the operational parameters. The operational parameters monitored may include the injection rate of the pumped fluid, the density of the pumped fluid or the bottomhole pressure of the well after the fluid is pumped. The method provides an increase to the stimulated reservoir volume (SRV).

This application claims the benefit of U.S. patent application Ser. No. 61/664,595, filed on Jun. 26, 2012.

FIELD OF THE INVENTION

The invention relates to a method of hydraulic fracturing and particularly to a method of improving the total surface area of a created or enlarged fracture and/or the complexity of the hydraulic fracture by altering stress conditions in the reservoir.

BACKGROUND OF THE INVENTION

Hydraulic fracturing is a stimulation process for creating high-conductivity communication with a large area of a subterranean formation. The process increases the effective wellbore area within the formation in order that entrapped oil or gas production can be accelerated. The efficiency of the process is often measured by the stimulated reservoir volume (SRV) of the formation.

During hydraulic fracturing, a fracturing fluid is pumped at pressures exceeding the fracture pressure of the targeted reservoir rock in order to create or enlarge fractures within the subterranean formation penetrated by the wellbore. The fluid used to initiate hydraulic fracturing is often referred to as the “pad”. In some instances, the pad may contain fine particulates, such as fine mesh sand, for fluid loss control. In other instances, the pad may contain particulates of larger grain in order to abrade perforations or near-wellbore tortuosity.

Once the fracture is initiated, subsequent stages of fluid containing chemical agents, as well as proppants, may be pumped into the created fracture. The fracture generally continues to grow during pumping and the proppants remain in the fracture in the form of a permeable “pack” that serves to “prop” the fracture open. Once the treatment is completed, the fracture closes onto the proppants. Increasing the fracturing fluid pressure ultimately causes an increase in the leak-off rate of the fluid through the faces of fractures which improves the ability of the proppant to pack within the fracture. Once the treatment is completed, the fracture closes onto the proppants. The proppants maintain the fracture open, providing a highly conductive pathway for hydrocarbons and/or other formation fluids to flow into the wellbore.

The treatment design of a hydraulic fracturing operation for a conventional reservoir generally requires the fracturing fluid to reach maximum viscosity as it enters the fracture. The viscosity of the fluid affects fracture length and width.

The viscosity of most fracturing fluids may be attributable to the presence of a viscosifying agent, such as a viscoelastic surfactant or a viscosifying polymer. An important attribute of any fracturing fluid is its ability to exhibit viscosity reduction after injection. Low viscosity fluids known as slickwater have also been used in the stimulation of low permeability formations, including tight gas shale reservoirs. Such reservoirs often exhibit a complex natural fracture network. Slickwater fluids typically do not contain a viscoelastic surfactant or viscosifying polymer but do contain a sufficient amount of a friction reducing agent to minimize tubular friction pressures. Such fluids, generally, have viscosities only slightly higher than unadulterated fresh water or brine. The presence of the friction reduction agent in slickwater does not typically increase the viscosity of the fluid by more than 1 to 2 centipoise (cP).

To effectively access tight formations, wells are often drilled horizontally and then subjected to one or more fracture treatments to stimulate production. Fractures propagated with low viscosity fluids exhibit smaller fracture widths than those propagated with higher viscosity fluids. In addition, low viscosity fluids facilitate increased fracture complexity in the reservoir during stimulation. This often results in the development of greater created fracture area from which hydrocarbons may flow into higher conductive fracture pathways. Further, such fluids introduce less residual damage into the formation in light of the absence of viscosifying polymer in the fluid.

In some shale formations, an excessively long primary fracture often results perpendicular to the minimum stress orientation. Typically, pumping of additional fracturing fluid into the wellbore simply extends the planar or primary fracture. In most instances, primary fractures dominate and secondary fractures are limited. Fracturing treatments which create predominately long planar fractures are characterized by a low contacted fracture face surface area, i.e., low SRV. Production of hydrocarbons from the fracturing network created by such treatments is limited by the low SRV.

Lately, slickwater fracturing has been used in the treatment of shale formations. However, the secondary fractures created by the operation are near to the wellbore where the surface area is increased. Slickwater fracturing is generally considered to be inefficient in the opening or creation of complex network of fractures farther away from the wellbore. Thus, while SRV is increased in slickwater fracturing, production is high only initially and then drops rapidly to a lower sustained production since there is little access to hydrocarbons far field from the wellbore.

Like slickwater fracturing, conventional fracturing operations typically render an undesirably lengthy primary fracture. While a greater number of secondary fractures may be created farther from the wellbore using viscous fluids versus slickwater, fluid inefficiency, principally exhibited by a reduced number of secondary fractures generated near the wellbore, is common in conventional hydraulic fracturing operations.

Recently, attention has been directed to alternatives for increasing the productivity of hydrocarbons far field from the wellbore as well as near wellbore. Particular attention has been focused on increasing the productivity of low permeability formations, including shale. Methods have been especially tailored to the stimulation of discrete intervals along the horizontal wellbore resulting in perforation clusters. While the SRV of the formation is increased by such methods, potentially productive reservoir areas between the clusters are often not stimulated. This decreases the efficiency of the stimulation operation. Methods of increasing the SRV by increasing the distribution of the area subjected to fracturing have therefore been sought.

SUMMARY OF THE INVENTION

The complexity of a fracture network may be enhanced during a hydraulic fracturing operation by monitoring operational parameters of the fracturing job and altering stress conditions in the well during the operation. In addition, the total surface area of the created fracture may be increased by such operations. The method provides an increase to the stimulated reservoir volume (SRV).

One or more operational parameters may be monitored. The common operational parameters which are monitored are the injection rate of the fluid, the density of the fluid and the bottomhole pressure of the well.

One or more operational parameters are assessed before a fluid stage is pumped and after the fluid stage is pumped. Stress conditions within the well may then be altered based on the difference between the monitored reading of the operational parameter after pumping of the fluid stage and a pre-determined target of the operational parameter. Thus, subsequent steps in the hydraulic fracturing operation are determined by the responses observed from monitoring one or more operational parameter(s).

In one embodiment, the operational parameter is monitored after the initial fracturing fluid or pad fluid is pumped into the formation which enlarges or creates initial fracture.

In another embodiment, the operational parameter may be monitored after any fluid stage which is pumped into the formation after the initial fracturing fluid or pad fluid.

In another embodiment, the operational parameter may be monitored during each fluid stage which is pumped into the formation.

When the operational parameter being monitored is different from the targeted operational parameter, the flow of fluid entering the formation may be diverted.

In one embodiment, the flow of fluid from a highly conductive primary fracture or fractures to lower conductive secondary fractures may be diverted after the operational parameter has been monitored.

In an embodiment, the flow of fluid into the formation may be diverted by changing the rate of injection of the fluid which is pumped into the formation after the operational parameter is monitored.

In another embodiment, the flow of fluid may be diverted by pumping into the formation, after the monitored stage is pumped, a diversion fluid which contains a chemical diverting agent.

In an embodiment, the chemical diverter used in the method described herein may be a compound of the formula:

or an anhydride thereof

wherein:

-   -   R¹ is —COO—(R⁵O)_(y)—R⁴;     -   R² and R³ are selected from the group consisting of —H and         —COO—(R⁵O)_(y)—R⁴;         -   provided that at least one of R² or R³ is —COO—(R⁵O)_(y)—R⁴             and         -   further provided that both R² and R³ are not             —COO—(R⁵O)_(y)—R⁴;     -   R⁴ is —H or a C₁-C₆ alkyl group;     -   R⁵ is a C₁-C₆ alkylene group; and     -   each y is 0 to 5;         In a preferred embodiment, the chemical diverter is phthalic         anhydride or terephthalic anhydride.

BRIEF DESCRIPTION OF THE DRAWINGS

In order to more fully understand the drawings referred to in the detailed description of the present invention, a brief description of each drawing is presented, in which:

FIG. 1 is a flow diagram of the method of the invention wherein continuous stages are pumped into a subterranean formation to enhance a fracture network.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Illustrative embodiments of the invention are described below as they might be employed in the operation and treatment of oilfield applications. In the interest of clarity, not all features of an actual implementation are described in this specification. It will of course be appreciated that in the development of any such actual embodiment, numerous implementation and/or specific decisions must be made to achieve the specific goals of the operator, which will vary from one implementation to another. Moreover, it will be appreciated that such a development effort might be complex and time-consuming, but may nevertheless be a routine undertaking for those of ordinary skill in the art having the benefit of this disclosure. Further aspects and advantages of the various embodiments of the invention will become apparent from consideration of the following description.

Steps of the hydraulic fracturing methods described herein are premised on results obtained from monitoring of one or more operational parameters during treatment of the well. The methods may be used to extend fractures or create a multiple network of fractures. As such, the methods may be used to enhance the complexity of a fracture network within a subterranean formation and to enhance production of hydrocarbons from the formation.

In the methods described herein, one or more operational parameters of a hydraulic fracturing operation are monitored after completion of a fluid pumping stage. In particular, the operational parameters are compared to targeted parameters pre-determined by the operator. Based on the comparison, stress conditions in the well may be altered before introduction of a successive fluid stage into the formation.

The term “successive fluid pumping stage” as used herein refers to the fluid pumping stage in a hydraulic fracturing operation which precedes another fluid pumping stage. The fluid pumping stage which immediately precedes the successive fluid pumping stage is referred to as the “penultimate fluid pumping stage”. Since the methods described herein may be a continuous operation or have repetitive steps, a successive fluid pumping stage may be between two penultimate fluid pumping stages. For example, a first successive fluid pumping stage may follow a first penultimate fluid pumping stage. When referring to a “second successive fluid pumping stage”, the first successive fluid pumping stage is the second penultimate fluid pumping stage and so on. A successive fluid pumping stage may be pumped into the wellbore following a period of time for the fluid of the penultimate fluid pumping stage to be diverted into the fracture created or enlarged by the penultimate fluid pumping stage.

Stress within the well may be determined by monitoring one or more operational parameters. Changes in one or more of the operational parameters are indications to the operator that fracture complexity and/or fracture geometry has changed and that Stimulated Reservoir Volume (SRV) has increased. For instance, stress noted within the formation may be indicative as to propagation of the fracture. The method of assessing stress within the well may include real-time modeling of the created fracture network using a simulator, such as MShale.

Thus, observance of trends and responses of operational parameters resulting from a penultimate fluid pumping stage may be used to control and dictate conditions of successive fluid pumping stage.

For instance, variances between one or more pre-determined operational parameters with the operational parameter after a second successive fluid pumping stage may indicate to the operator whether fractures have been created or whether fluid has been lost during the second penultimate fluid pumping stage to intercepting fractures.

Based upon the change in one or more of the operational parameters, stress within the reservoir may be altered. For instance, where propagation is insufficient as determined by the operator after a fluid pumping stage, the operator may cause an alteration of the reservoir stress field. The methods defined herein may thus be used to increase the complexity of the fractures by artificially adding a resistance in the fracture such that new fracture paths are opened that would otherwise not be able to be created or enlarged. Thus, fracture complexity may be increased as the differential stress or propagation pressure increases. This may occur without a sustained increase in fracturing pressure.

In a preferred embodiment, one or more of the following operational parameters are monitored during the fracturing operation: the rate of injection of the fluid, the bottomhole pressure of the well (measured as Net Pressure) or the density of the fluid pumped into the formation. The monitoring of such operational parameter(s) may be used to create a network of fractures at near-wellbore as well as far-wellbore locations by altering stress conditions within the reservoir.

The injection rate of the fluid is defined as the maximum rate of injection that the fluid may be pumped into the formation beyond which the fluid is no longer capable of fracturing the formation (at a given pressure). The maximum rate of injection is dependent on numerous constraints including the type of formation being fractured, the width of the fracture, the pressure which the fluid is pumped, permeability of the formation, etc. The maximum rate of injection is pre-determined by the operator. Changes in Net Pressure are indications of change in fracture complexity and/or change in fracture geometry thus producing greater Stimulated Reservoir Volume (SRV). The Net Pressure that is observed during a hydraulic fracturing treatment is the difference between the fluid pressure in the fracture and the closure pressure (CP) of the formation.

-   -   Fluid pressure in the fracture=Bottom Hole Treating Pressure         (BHTP).     -   BHTP can be calculated from: Surface Treating Pressure         (STP)+Hydrostatic Head (HH)−Total Delta Friction Pressures         (Δp_(friction)=pipe friction+perforation friction+tortuosity).

Determination of closure pressure, pipe friction, perforation friction, and presence of tortuosity is critical. A diagnostic treatment using a step down rate and observance of pressure decline should be conducted if the formation can sustain a pumping shut down without limiting the desired injection rate upon restarting the injection to obtain these necessary parameters. The bottomhole pressure (also known as the measured or calculated bottomhole pumping pressure or measured or calculated bottomhole treating pressure) (BHP) is a measurement or calculation of the fluid pressure in a fracture. It is needed to determine the Net Pressure defined as: P _(net) =STP+HH−P _(fric) −CP Although many conventional fracture treatments result in bi-wing fractures, there are naturally fractured formations that provide the geomechanical conditions that enable hydraulically induced discrete fractures to be initiated and propagate in multiple planes as indicated by microseismic mapping. The dominant or primary fractures propagate in the x-z plane perpendicular to the minimum horizontal stress, o^(•) ₃. The y-z and x-y plane fractures propagate perpendicular to the o^(•) ₂ and o^(•) ₁, stresses, respectively. The discrete fractures created in the x-z and y-z planes are vertical, while the induced fractures created in the x-y plane are horizontal. The microseismic data collected during a fracture treatment can be a very useful diagnostic tool to calibrate the fracture model by inferring DFN areal extent, fracture height and half-length and fracture plan orientation. Integrating minifrac analysis, hydraulic fracturing and microseismic technologies with the production response for multiple transverse vertical fractures provides a methodology to improve the stimulation program for enhanced gas production.

Programs or models for modeling or predicting BHP are known in the art. Examples of suitable models include, but are not limited to, “MACID” employed by Baker Hughes Incorporated and available from Meyer and Associates of Natrona Heights, Pa.; “FRACPRO” from Resources Engineering Services; and “FRACPRO PT”, available from Pinnacle Technology. BHP may further be calculated based on formation characteristics. See, for instance, Hannah et al, “Real-time Calculation of Accurate Bottomhole Fracturing Pressure From Surface Measurements Using Measured Pressures as a Base”, SPE 12062 (1983); Jacot et al, “Technology Integration—A Methodology to Enhance Production and Maximize Economics in Horizontal Marcellus Shale Wells”, SPE 135262 (2010); and Yeager et al, “Injection/Fall-off Testing in the Marcellus Shale: Using Reservoir Knowledge to Improve Operational Efficiency”, SPE 139067 (2010).

The objective is therefore to observe changes in one or more of the operational parameters and alter the operational parameter(s) response by using diversion. The value of that change will be formation and area specific and can even vary within the same formation within the same lateral. Those differences arise in the varying minimum and maximum stress planes. In some instances there is very low anisotropy resulting in “net” fracture development. In other areas the anisotropy is very high and a conventional profile may dominate the fracture complexity.

Since the presence of low to high anisotropy, as well as anisotropy in between low anisotropy and high anisotropy, can often not be ascertained through a mini-frac treatment, net pressure changes are often the key operational parameter used to assess stress conditions. Downward slopes, negative, are indications of height growth while positive slopes of <45° will be indications of height and extension growth depending on slope. Thus, changes in one or more of the operational parameters may be indicative of fracture height and growth. For instance, while small changes in BHP may be due to varying frictional pressures of fluids (and proppants) as the fluid travels through the fracture system, sustained negative downward slopes may be indicative of height growth, positive slopes of less than 45° may be indicative of height and extension growth.

Stress conditions in the well may be altered by diverting fluid flow such that the fluid pumped into the formation will more readily flow into less conductive secondary fractures within the formation. Such diversion limits injectivity in the primary fractures and stress pressures within the formation. As such, fluid flow may be diverted from a highly conductive primary fracture(s) to less conductive secondary fractures. Since conductivity is permeability multiplied by injection geometry, this is synonymous to the statement that fluid flow may be diverted from a high permeability zone to a low permeability zone. Further, since conductivity is a function of the relative resistance to inflow, the reference to a conductive fracture as used herein is considered synonymous to a conductive reservoir area. Alteration of the local stress conditions provides greater complexity to the created fracture network and/or improves the reservoir coverage of the stimulation treatment.

Thus, the methods described herein can be used to extend or increase a fracture profile. In addition, the methods described herein may be used to create a multiple of fractures originating from the original primary fracture wherein each successive stage creates a fracture having an orientation distinct from the directional orientation of the fracture created by the penultimate fracture.

When necessary, the flow of fluid within the formation may be diverted by subjecting the formation to one or more diversion stages.

Fluid flow may be diverted from highly conductive fractures to less conductive fractures by changing the injection rate and viscosity of the fluid into the formation.

Diversion may also occur by introduction of a diverter fluid or slug containing a chemical diverting agent into the formation. This may cause displacement of the diverter slug beyond the near wellbore.

Further, a combination of a diverter fluid or slug may be used with a change in the injection rate and/or viscosity of fluid into the formation in order to effectuate diversion from a highly conductive fracture to a less conductive fracture. The diverter fluid may contain a chemical diverting agent. The diverter fluid may be pumped into the formation at a rate of injection which is different from the rate of injection of a penultimate fluid pumping stage but rate is necessarily limited to a rate low enough so as not to exceed the predetermined pressure limitations observed with the surface monitoring equipment.

The diversion stage serves to divert fluid flow away from highly conductive fractures and thus promotes a change in fracture orientation. This causes fluid entry and extension into the secondary fractures. For instance, a reduction in injection rate may be used to allow the shear thinning fluid to build sufficient low shear rate viscosity for adequate pressure diversion for the changing fracture orientation created by the secondary fractures. In addition, reduction in injection rate may contribute to the opening and connecting of secondary fractures.

In an embodiment, diversion fluid and/or the change in injection rate of pumped fluid may create at least one secondary fracture in a directional orientation distinct from the directional orientation of the primary fracture. Thus, at some point along the primary fracture the resistance to flow of the viscosity and resultant increased pressure induces the successive stage fluid to be diverted to a new area of the reservoir such that the increase in SRV occurs.

After diversion, the flow of fluid introduced into the low permeability zone of the formation may be impeded. The operational parameter being monitored may then be compared to the pre-determined operational parameter. Subsequent fluid stages may be introduced into the formation and the need for diversionary stages will be premised on the difference between the monitored operational parameter following the subsequent fluid stage with the targeted operational parameter.

After the diverter fluid is pumped or after the injection rate of fluid into the formation is modified, the operational parameter being monitored may then be noted. If the operational parameter is less than the target of the operational parameter, the fluid flow may continue to be diverted in another diversionary step.

The process may be repeated until the SRV desired is obtained or until the complexity of the fracture is attained which maximizes the production of hydrocarbons from the formation.

Thus, by monitoring an operational parameter and observing changes in the operational parameter, stresses within the formation may be altered. The value of any diversionary step will be formation and area specific and differences may be noted in varying minimum and maximum stress planes within the same lateral. For instance, in some instances very low anisotropy will result in net fracture development. In other areas very high anisotropy may dominate the fracture complexity.

In one preferred embodiment, the bottomhole pressure of fluid after pumping a first stage is compared to the targeted pre-determined bottomhole pressure of the well. The first stage may be the stage which enlarges or creates a fracture. Based on the difference in the bottomhole pressure, the flow of fluid from a highly conductive primary fracture to less conductive secondary fractures may be diverted by introducing into the formation a chemical diverter. The bottomhole pressure after the diversion may then be compared to the pre-determined bottomhole pressure. The flow of fluid introduced into the low conductive fracture in the next stage may then be impeded. Subsequent fluid stages may be introduced into the formation and the need for subsequent diversionary stages will be premised on the difference between the bottomhole pressure after a preceding stage and the pre-determined bottomhole pressure.

In another preferred embodiment, the maximum injection rate which a fluid may be pumped after the pumping of a first fluid stage is compared to the targeted injection rate. The first stage may be the stage which enlarges or creates a fracture. Based on the difference in the rates of injection, the flow of fluid from a highly conductive primary fracture to less conductive secondary fractures may be diverted by introducing into the formation a chemical diverter. The maximum rate of injection after the diversion may then be compared to the pre-determined rate of injection. The flow of fluid introduced into the low conductive fracture in the next stage may then be impeded. Subsequent fluid stages may be introduced into the formation and the need for subsequent diversionary stages will be premised on the difference between the maximum rate of injection after a preceding stage and the pre-determined injection rate.

In another preferred embodiment, the density of a fluid stage after pumping a first stage is compared to a targeted density of a fluid stage. Based on the difference in fluid density, the flow of fluid from a highly conductive primary fracture to less conductive secondary fractures may be diverted by the injection rate of the fluid or by introduction of a chemical diverter into the formation. The density of the fluid stage after the diversion may then be compared to the pre-determined fluid density. The flow of fluid introduced into the low conductive fracture in the next stage may then be impeded. Subsequent fluid stages may be introduced into the formation and the need for diversionary stages will be premised on the difference between the fluid stage density after a preceding stage and the pre-determined fluid density.

In an embodiment, the diversion fluid pumped into the formation in response to a monitored operational parameter may contain a chemical diverter (which may be partially, but not fully, dissolved in at in-situ reservoir conditions) in combination with relatively lightweight particulates having an apparent specific gravity less than or equal to 2.45. Preferably, relatively lightweight particulates are neutrally buoyant in the fluid which further contains the chemical diverter.

Chemical diverters, optionally in combination with relatively lightweight particulates, may be used to control fluid loss to natural fractures and may be introduced into productive zones of a formation having various permeabilities. The diverter, optionally in combination with relatively lightweight particulates, is capable of diverting a well treatment fluid from a highly conductive fracture to less conductive fractures within a subterranean formation.

The diverter may be partially, but not fully, dissolvable in fluids at in-situ reservoir conditions. Any portion of the diverter which remains as an undissolved confined particulate, after being pumped into the formation, may function as a proppant. The amount of diverter which is dissolvable in at in-situ conditions is typically from about 75% to about 95%. Preferably, the amount of the diverter which is dissolvable in the fluid is about 90%. At such concentrations, a partial monolayer of the diverter may function as proppant. Over time, all of the diverter may eventually dissolve when fracture closure no longer presents a concern to the operator.

The solid particulates typically bridge the flow spaces on the face of the formation and form a filter cake. For instance, when employed in acid fracturing, the particulates are of sufficient size to bridge the flow space (created from the reaction of the injected acid with the reservoir rock) without penetration of the matrix. By being filtered at the face of the formation, a relatively impermeable or low permeability filter cake is created on the face of the formation. The pressure increase through the filter cake also increases the flow resistance and diverts treatment fluid to less permeable zones of the formation.

The size distribution of the particulates should be sufficient to block the penetration of the fluid into the high permeability zone of the formation. The filter cake is more easily formed when at least 60%, more preferably 80%, of the chemical diverter and/or relatively lightweight particulates within the well treatment fluid have a particle size between from about 150 μm to about 2000 μm.

When used in stimulation operations, the particle size of the particulates is such that the particulates may form a bridge on the face of the rock. Alternatively, the particle size of the particulates may be such that they are capable of flowing into the fracture and thereby pack the fracture in order to temporarily reduce the conductivity of at least some of the fractures in the formation.

Relatively lightweight particulates may also serve as proppant in any of the fluid stages introduced into the formation. In addition, conventional proppants, such as bauxite and sand may be used as proppant in any of the fluid stages.

The first stage may consist of pumping into the formation a fluid at a pressure sufficient to either propagate or enlarge a primary fracture. This fluid may be a pad fluid. Fracture conductivity may be improved by the incorporation of a small amount of proppant in the fluid. Typically, the amount of proppant in the pad fluid is between from about 0.12 to about 24, preferably between from about 0.6 to about 9.0, weight percent based on the total weight percent of the fluid.

Following the injection of the pad fluid, a viscous fluid may then be introduced into the wellbore. The viscous fluid typically has a viscosity greater than about 10,000 cP at a shear rate of 0.01 sec⁻¹. The diversion stage may be pumped into the formation after the first stage or between any of the successive stages or penultimate stages.

Between any penultimate stage and successive stage, pumping may be stopped and a pad fluid containing a proppant may be pumped into the reservoir to assist in the creation or enlargement of secondary fractures.

In a preferred embodiment, the proppant is a relatively lightweight or substantially neutrally buoyant particulate material or a mixture thereof. Such proppants may be chipped, ground, crushed, or otherwise processed. By “relatively lightweight” it is meant that the proppant has an apparent specific gravity (ASG) that is substantially less than a conventional proppant employed in hydraulic fracturing operations, e.g., sand or having an ASG similar to these materials. Especially preferred are those proppants having an ASG less than or equal to 3.25. Even more preferred are ultra lightweight proppants having an ASG less than or equal to 2.25, more preferably less than or equal to 2.0, even more preferably less than or equal to 1.75, most preferably less than or equal to 1.25 and often less than or equal to 1.05.

The proppant may further be a resin coated ceramic proppant or a synthetic organic particle such as nylon pellets, ceramics. Suitable proppants further include those set forth in U.S. Patent Publication No. 2007/0209795 and U.S. Patent Publication No. 2007/0209794, herein incorporated by reference. The proppant may further be a plastic or a plastic composite such as a thermoplastic or thermoplastic composite or a resin or an aggregate containing a binder.

By “substantially neutrally buoyant”, it is meant that the proppant has an ASG close to the ASG of an ungelled or weakly gelled carrier fluid (e.g., ungelled or weakly gelled completion brine, other aqueous-based fluid, or other suitable fluid) to allow pumping and satisfactory placement of the proppant using the selected carrier fluid. For example, urethane resin-coated ground walnut hulls having an ASG of from about 1.25 to about 1.35 may be employed as a substantially neutrally buoyant proppant particulate in completion brine having an ASG of about 1.2. As used herein, a “weakly gelled” carrier fluid is a carrier fluid having minimum sufficient polymer, viscosifier or friction reducer to achieve friction reduction when pumped down hole (e.g., when pumped down tubing, work string, casing, coiled tubing, drill pipe, etc.), and/or may be characterized as having a polymer or viscosifier concentration of from greater than about 0 pounds of polymer per thousand gallons of base fluid to about 10 pounds of polymer per thousand gallons of base fluid, and/or as having a viscosity of from about 1 to about 10 centipoises. An ungelled carrier fluid may be characterized as containing about 0 to <10 pounds of polymer per thousand gallons of base fluid. (If the ungelled carrier fluid is slickwater with a friction reducer, which is typically a polyacrylamide, there is technically 1 to as much as 8 pounds of polymer per thousand gallons of base fluid, but such minute concentrations of polyacrylamide do not impart sufficient viscosity (typically<3 cP) to be of benefit).

Other suitable relatively lightweight proppants are those particulates disclosed in U.S. Pat. Nos. 6,364,018, 6,330,916 and 6,059,034, all of which are herein incorporated by reference. These may be exemplified by ground or crushed shells of nuts (pecan, almond, ivory nut, brazil nut, macadamia nut, etc); ground or crushed seed shells (including fruit pits) of seeds of fruits such as plum, peach, cherry, apricot, etc.; ground or crushed seed shells of other plants such as maize (e.g. corn cobs or corn kernels), etc.; processed wood materials such as those derived from woods such as oak, hickory, walnut, poplar, mahogany, etc. including such woods that have been processed by grinding, chipping, or other form of particalization. Preferred are ground or crushed walnut shell materials coated with a resin to substantially protect and water proof the shell. Such materials may have an ASG of from about 1.25 to about 1.35.

Further, the relatively lightweight particulate for use in the invention may be a selectively configured porous particulate, as set forth, illustrated and defined in U.S. Pat. No. 7,426,961, herein incorporated by reference.

In a preferred embodiment, at least one diversion step in the method described herein consists of pumping into the formation a fluid containing a chemical diverter in combination with non-dissolvable relatively lightweight particulates including those referenced above. The chemical diverting agent may be partially, but not fully, dissolvable at in-situ reservoir conditions. In another preferred embodiment, the diverting stage contains a chemical diverter with a relatively lightweight particulate substantially naturally buoyant in the fluid.

The fluid phase of the treatment fluid containing the particulates is any fluid suitable for transporting the particulate into a well and/or subterranean formation such as water, salt brine and slickwater. Suitable brines including those containing potassium chloride, sodium chloride, cesium chloride, ammonium chloride, calcium chloride, magnesium chloride, sodium bromide, potassium bromide, cesium bromide, calcium bromide, zinc bromide, sodium formate, potassium formate, cesium formate, sodium acetate, and mixtures thereof. The percentage of salt in the water preferably ranges from about 0% to about 60% by weight, based upon the weight of the water.

The fluid of the treatment fluid may be foamed with a liquid hydrocarbon or a gas or liquefied gas such as nitrogen or carbon dioxide.

In addition, the fluid may further be foamed by inclusion of a non-gaseous foaming agent. The non-gaseous foaming agent may be amphoteric, cationic or anionic. Suitable amphoteric foaming agents include alkyl betaines, alkyl sultaines and alkyl carboxylates, such as those disclosed in U.S. Patent Publication No. 2010/0204069, herein incorporated by reference. Suitable anionic foaming agents include alkyl ether sulfates, ethoxylated ether sulfates, phosphate esters, alkyl ether phosphates, ethoxylated alcohol phosphate esters, alkyl sulfates and alpha olefin sulfonates. Suitable cationic foaming agents include alkyl quaternary ammonium salts, alkyl benzyl quaternary ammonium salts and alkyl amido amine quaternary ammonium salts.

The pH of the fluid containing the particulates may further be adjusted when desired. When adjusted, it typically has a value of about 6.5 or more, 7 or more, 8 or more, 9 or more, between 9 and 14, and, most preferably, between 7.5 and 9.5. The pH may be adjusted by any means known in the art, including adding acid or base to the fluid, or bubbling carbon dioxide through the fluid.

The fluid may be gelled or non-gelled. Typically the fluid is gelled by the inclusion of a viscosifying agent such as a viscosifying polymer or viscoelastic fluid. The fluid may contain a crosslinking agent though a crosslinking agent is not required. Generally, the viscosity of the fluid is greater than or equal to 10 cP at room temperature.

An illustrative process defined herein is shown in FIG. 1 wherein the operational parameter being monitored is Net Pressure and wherein the fluid volume of each of the stages has been set by an operator; the total volume of the fluid being broken into four or more stages. Each stage may be separated by a period of reduced or suspended pumping for a sufficient duration to allow the staged fluid in the reservoir to flow into a created or enlarged fracture.

The injection rate and the STP are established by the operator. The fracturing operation is initialized by pumping into the formation a first fluid stage comprising a pad fluid or slickwater. The Net Pressure response of the treatment is monitored. A plot of Net Pressure verses time on a log-log scale may be used to identify trends during the treatment. At the end of the fluid pumping stage, the net pressure value and slope is evaluated.

Where the pressure is equal to or greater than the pre-determined BHP, then additional fracturing fluid is pumped into the formation as a second or successive stage and it is not necessary to divert the flow of fluid from a high permeability zone to a lower permeability zone. Where the BHP (as measured by net Pressure) is less than the pre-determined BHP, then a diverter fluid containing a chemical diverting agent or slug is pumped into the formation. The divert slug is displaced beyond near wellbore. The diverter fluid may be over-displaced beyond the wellbore and into the fracture network. The net pressure response is then observed when the diversion stage is beyond the wellbore and in the fracture network. If the net pressure response is considered to be significant by the operator indicating a change in fracture complexity and/or geometry then an additional fracturing fluid is pumped into the formation in order to stimulate a larger portion of the reservoir. At the end of pumping stage, net pressure is again evaluated and the possibility of running another diversion stage is evaluated. If the net pressure response is not considered to be significant by the operator, then an additional diversion stage is pumped into the formation and the net pressure response is evaluated when the diversion stage is beyond the wellbore and in the fracture network. The volume and quantity of the successive diversion stage may be the same as the penultimate diversion stage or may be varied based on the pressure response. The injection rate of the pumped fluid may also be changed once the diversion stage is in the fracture system to affect the pressure response. If the net pressure response is too significant in size indicating a bridging of the fracture without a change in fracture complexity and/or geometry, additional pumping may or may not be warranted. For example if the pressure response is too high the pressure limitations of the tubulars may prevent a continuation of the treatment due to rate and formation injectivity limitations. The running of additional diversion stages may be repeated as necessary until a desired pressure response is achieved and the fracture complexity/geometry is maximized, the well treatment injection is ceased and the well may then be shut in, flowed back or steps may be undertaken to complete subsequent intervals

If the BHP is less than the pre-determined BHP, then a successive stage is pumped into the formation and the process repeated. The process may be continuous and may be repeated multiple times throughout the course of the pumping treatment to attain development of a greater fracture area and greater fracture complexity than that which would be attained in the absence of such measures.

The diversion stage either achieves or directly impacts the monitored BHP so as to artificially increase the differential pressure. This differential pressure may not be obtained without the diverting fluid. The increased pressure differential causes sufficient stress differential to create or enlarge a smaller fracture. The effectiveness of the diversion may then be ascertained by either increasing the volume of a chemical diverter or the size of the chemical diverter. The increase in BHP from the diverting stage limits the fluid volume introduced into the formation which would otherwise be larger volume. Thus, a benefit of the process is that a decreased amount of water may be used to achieve a given degree of stimulation.

In place of the BHP, other parameters, such as fluid density and injection rate of the fluid, may be used as the operational parameter in FIG. 1. With any of these parameters, the operator will determine the targeted level based on the characteristics of the well and formation being treated. Reduction of the injection rate of the fluid further may facilitate the diversion of flow from narrow intersecting fractures especially when accompanied by increases in the treating pressure. An increase in the injection rate of the fluid renders greater propagation in the more primary fractures within the formation.

The diverter of the diversion fluid for use in the invention may be any diverter known in the art. Especially preferred as diverter are those particulates having the structural formula (I):

wherein:

-   -   R¹ is —COO—(R⁵O)_(y)—R⁴;     -   R² and R³ are selected from the group consisting of —H and         —COO—(R⁵O)_(y)—R⁴;         -   provided that at least one of R² or R³ is —COO—(R⁵O)_(y)—R⁴             and         -   further provided that both R² and R³ are not             —COO—(R⁵O)_(y)—R⁴;     -   R⁴ is —H or a C₁-C₆ alkyl group;     -   R⁵ is a C₁-C₆ alkylene group; and     -   each y is 0 to 5.         Alternatively, the particulates may be an anhydride of the         compound of structural formula (I).

In a preferred embodiment, R² of the compound of formula (I) is —H and R³ is —COO—(R⁵O)_(y)—R⁴. In an especially preferred embodiment, the compound of formula (I) is phthalic acid (wherein y is 0 and R⁴ is —H). In another preferred embodiment, the compound of formula (I) is phthalic acid anhydride.

Still in another preferred embodiment, R² of the compound of formula (I) is —COO—(R⁵O)_(y)—R⁴ and R² is —H. In an especially preferred embodiment, the compound of formula (I) is terephthalic acid (wherein y is 0 and R⁴ is —H). In another preferred embodiment, the compound of formula (I) is terephthalic acid anhydride.

Such diverters and fluids containing the same are set forth in U.S. patent application Ser. No. 13/928,006, filed on Jun. 26, 2013, herein incorporated by reference.

The particulates may be of any size or shape and the particulates within a given diversionary stage may be of varying size. For instance, the particulates may be substantially spherical, such as being beaded, or pelleted. Further, the particulates may be non-beaded and non-spherical such as an elongated, tapered, egg, tear-drop or oval shape or mixtures thereof. For instance, the particulates may have a shape that is cubic, bar-shaped (as in a hexahedron with a length greater than its width, and a width greater than its thickness), cylindrical, multi-faceted, irregular, or mixtures thereof. In addition, the particulates may have a surface that is substantially roughened or irregular in nature or a surface that is substantially smooth in nature. Moreover, mixtures or blends of particulates having differing, but suitable, shapes for use in the disclosed method further be employed.

The amount of particulates of formula (I) in the diversion fluid may be from about 0.01 to about 30 volume percent (based on the total volume of the fluid) and may be partially dissolvable at in-situ downhole conditions. In some instances, the particulates of formula (I) are fully dissolvable at downhole conditions.

The particulates are particularly effective when placed into wells having bottomhole temperatures between from about 175° F. to about 250° F.

When used as a diverter, the fluid containing the particulates may also be pumped directly to the high permeability zone of the well formation. The majority of the diverting fluid will enter into the high permeability or non-damaged zone and form a temporary “plug” or “viscous pill” while the lower permeability zone has little invasion. This temporary “viscous pill” causes a pressure increase and diverts the fluid to a lower permeability portion of the formation. The particulates are capable of being spread deeper into subterranean formations than diverting agents of the prior art.

Once in place, the viscous pill formed from the diverter will have a finite depth of invasion which is related to the pore throat diameter. For a given formation type, the invasion depth is directly proportional to the nominal pore throat diameter of the formation. Since varying depths of invasion occur throughout the formation based upon the varying permeability or damage throughout the treated zone, the ability of the treatment fluid to invade into pore throats is dependent on the difference between pore throat sizing of the damaged and non-damaged formation. Invasion depths will normally be greater in the cleaner or non-damaged portion of the formation (larger pore throats) than in the lower permeability or damaged zones (smaller or partially filled pore throats). With a greater depth of invasion in the cleaner sections of the formation, more of the diverter may be placed in these intervals.

The methods described herein may be used in the fracturing of formations penetrated by horizontal as well as vertical wellbores.

The formation subjected to the treatment of the invention may be a hydrocarbon or a non-hydrocarbon subterranean formation. The high permeability zone of the formation into which the fluid containing the diverter is pumped may be natural fractures. When used with low viscosity fracturing fluids, the particulates of formula (I) are capable of diverting fracturing fluids to extend fractures and increase the stimulated surface area.

The invention has particular applicability to the stimulation of carbonate formations, such as limestone, chalk or dolomite as well as subterranean sandstone or siliceous formations in oil and gas wells, including quartz, clay, shale, silt, chert, zeolite, or a combination thereof.

In another preferred embodiment, the method may be used in the treatment of coal beds having a series of natural fractures, or cleats, for the recovery of natural gases, such as methane, and/or sequestering a fluid which is more strongly adsorbing than methane, such as carbon dioxide and/or hydrogen sulfide.

From the foregoing, it will be observed that numerous variations and modifications may be effected without departing from the true spirit and scope of the novel concepts of the invention. 

What is claimed is:
 1. A method of enhancing the complexity of a fracture network within a hydrocarbon-bearing subterranean formation penetrated by a well by subjecting the formation to a hydraulic fracturing operation in multiple pumping stages, wherein in a first stage a fluid is introduced into the well at a pressure sufficient to enlarge or create a fracture, the method comprising: (a) defining a target reading for at least one of the following operational parameters: (i) an injection rate of the fluid, (ii) density of the fluid; or (iii) a bottomhole pressure of the well; (b) pumping a first stage of a first fluid into the formation and creating or enlarging a fracture; (c) measuring at least one of the operational parameters of step (a) after the first fluid is pumped into the formation; comparing the measured operational parameter with the defined target reading of the operational parameter; and determining stress in the well from the comparison; (d) altering stress in the well based on the comparison by at least one of the following: (i) varying the injection rate of a second fluid pumped into the formation in a stage successive to the first stage; or (ii) promoting a change in fracture orientation by pumping a diverting agent into the formation after the first stage wherein the diverting agent bridges flow spaces into the created or enlarged fracture and then pumping a second fluid in a successive stage after pumping of the diverting agent wherein flow of the second fluid pumped in the successive stage is diverted from highly conductive fractures to less conductive fractures; (e) determining stress in the well by taking a second measurement of at least one of the operational parameters of step (a); and comparing the second measurement of the operational parameter with another defined target of the operational parameter; and (f) altering stress in the well based on the comparison of step (e) by varying the injection rate of fluid pumped into the formation in a next successive stage or pumping a second diverting agent into the formation wherein the stimulated reservoir volume after the stress is altered is greater than the stimulated reservoir volume after step (d).
 2. The method of claim 1, wherein the diverting agent is of the formula:

or an anhydride thereof wherein: R¹ is —COO—(R⁵O)_(y)—R⁴; R² and R³ are selected from the group consisting of —H and —COO—(R⁵O)_(y)—R⁴; provided that at least one of R² or R³ is —COO—(R⁵O)_(y)—R⁴ and further provided that both R² and R³ are not —COO—(R⁵O)_(y)—R⁴; R⁴ is —H or a C₁-C₆ alkyl group; R⁵ is a C₁-C₆ alkylene group; and each y is 0 to
 5. 3. The method of claim 1, wherein the diverting agent is phthalic anhydride or terephthalic anhydride.
 4. The method of claim 1, wherein the first fluid of (b) further comprises a proppant.
 5. The method of claim 4, wherein the proppant has an apparent specific gravity less than or equal to 2.25.
 6. The method of claim 1, wherein the subterranean formation is shale.
 7. The method of claim 1, wherein the process is continuous. 